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oai:www.ideals.illinois.edu:2142/84194 2023-07-11 col_2142_5131 col_2142_14789 com_2142_5130 com_2142_14788 com_2142_8903

van der Donk, Wilfred A. McGinley, Christopher 2015-09-25T22:13:24Z 2015-09-25T22:13:24Z 10000-01-01 2005 2005 Finally, the syntheses of site-specifically deuterated arachidonic acids containing a remote tritium label are reported. These radiolabeled substrates would allow the characterization of the initial radical intermediate for PGHS under aerobic conditions and enzyme turnover. The substrates could also be used to investigate other oxygenase enzymes, such as lipoxygenases and aspirin-treated PGHS. Made available in DSpace on 2015-09-25T22:13:24Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 3199081.pdf: 4642854 bytes, checksum: 54674e7025d98d17375ea1e561c5b14c (MD5) Previous issue date: 2005 Embargo set by: Seth Robbins for item 85475 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs U of I Only 210 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2005. http://hdl.handle.net/2142/84194 (MiAaPQ)AAI3199081 eng Chemistry, Biochemistry Part I. A Novel Vitamin B(12) Catalyzed Carbon-Carbon Bond Forming Reaction: Mechanistic Investigations and Aryl Alkene Cyclization. Part II. Mechanistic Investigation of Prostaglandin H Synthase Through the Synthesis of Site Specifically Substituted Arachidonic Acids text Chemistry Chemistry University of Illinois at Urbana-Champaign Dissertation Ph.D.