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oai:www.ideals.illinois.edu:2142/84283 2023-07-11 col_2142_5131 col_2142_14789 com_2142_5130 com_2142_14788 com_2142_8903

2007 Denmark, Scott E. Tymonko, Steven 2015-09-25T22:13:48Z 2015-09-25T22:13:48Z 10000-01-01 2007 Mechanistic investigations of the palladium-catalyzed cross-coupling of aryldimethylsilanolates demonstrated that transmetalation proceeds directly from an arylpalladium(II) silanolate intermediate without external activation. Arylpalladium(II) silanolate complexes bearing phosphine ligands were isolated and characterized. These complexes produce biaryl products via ligand dissociation and transmetalation. Made available in DSpace on 2015-09-25T22:13:48Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 3290408.pdf: 11000008 bytes, checksum: 20f4838d4e71109a64a38f5eafe56fa8 (MD5) Previous issue date: 2007 Embargo set by: Seth Robbins for item 85564 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs U of I Only 587 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2007. http://hdl.handle.net/2142/84283 (MiAaPQ)AAI3290408 eng Chemistry, Organic Palladium-Catalyzed Cross-Coupling Reactions of Organosilanols: I. New Methods That Employ Alkynylsilanols and Bissilyl Reagents. II. Mechanistic Analysis of the Cross-Coupling of Aryldimethylsilanolates text Chemistry Chemistry University of Illinois at Urbana-Champaign Dissertation Ph.D.