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Zimmerman, Steven C. Todd, Eric 2015-09-25T22:13:48Z 2015-09-25T22:13:48Z 10000-01-01 2007 2007 There is currently no common framework to discuss the quality of these more complex multi-component recognition systems. Part 2 of this dissertation reports undesired, cross-recognition in several commonly used triply and quadruply hydrogen-bonded complexes to assess the likelihood of orthogonal recognition. Modeling of the equilibria in several multi-component systems allows us to introduce a framework for discussing fidelity and the requirements for producing complex supramolecular systems capable of programmed self assembly. Made available in DSpace on 2015-09-25T22:13:48Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 3301236.pdf: 3604566 bytes, checksum: 8a7e243d855f0dfbd0b4bdf128a43a95 (MD5) Previous issue date: 2007 Embargo set by: Seth Robbins for item 85569 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs U of I Only 161 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2007. http://hdl.handle.net/2142/84288 (MiAaPQ)AAI3301236 eng Chemistry, Polymer Part I. Supramolecular Star Polymers Based on Ditopic Hydrogen-Bonding Modules. Part II. The Concept of Fidelity as a Framework for Evaluating the Behavior of Complex Supramolecular Systems text Chemistry Chemistry University of Illinois at Urbana-Champaign Dissertation Ph.D.