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Shapley, Patricia A. Liang, Hong-Chang 2015-09-25T22:14:14Z 2015-09-25T22:14:14Z 10000-01-01 1997 1997 Chapter 4. The synthesis and reactivity of several ruthenium(VI) and osmium(VI) sulfido complexes are reported. The triruthenium sulfido complexes (PPh$\sb4$) ($\rm\{Ru(N)R\sb2\}\sb3(\mu\sb3$-S)$\sb2\rbrack,$ (19, R = Me; 20, R = $\rm CH\sb2SiMe\sb3)$ react with $\rm MeOSO\sb2CF\sb3$ to form $\mu\sb3$-thiolate complexes $\rm\{Ru(N)R\sb2\}\sb3(\mu\sb3$-SMe)($\mu\sb3$-S) (22, R = $\rm CH\sb2SiMe\sb3$; 23, R = Me). Complex 19 reacts with ($\rm Cu(PPh\sb3)\sb2(NCMe)\sb2\rbrack\lbrack BF\sb4\rbrack$ to form ($\rm Cu(PPh\sb3)\sb2\rbrack\lbrack\{Ru(N)R\sb2\}\sb3(\mu\sb3$-S)$\sb2\rbrack,$ 24. Made available in DSpace on 2015-09-25T22:14:14Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 9812682.pdf: 3598558 bytes, checksum: b43533d1aba314bc6b9557aa1d52397d (MD5) Previous issue date: 1997 Embargo set by: Seth Robbins for item 85665 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs U of I Only 133 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1997. http://hdl.handle.net/2142/84384 (MiAaPQ)AAI9812682 eng Chemistry, Inorganic Synthesis and Reactivity of Trimethylsilylthiolate Compounds: Precursors for Heterometallic Complexes text Chemistry Chemistry University of Illinois at Urbana-Champaign Dissertation Ph.D.