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Nieman, T.A. Sweedler, J.V. Shultz, Loranelle Louise 2015-09-25T22:14:16Z 2015-09-25T22:14:16Z 10000-01-01 1997 1997 A post-column CL detection method for capillary electrophoresis (CE) was developed in which the capillary effluent was collected on a membrane which had been coated with bis(2,4,6-trichlorophenyl)oxalate, a CL reagent. After the CE run, the CL reaction was initiated on the membrane by applying hydrogen peroxide, a scientific CCD camera imaged the resultant CL emission, and an electropherogram was reconstructed. This post-column detection scheme decouples the separation parameters from detection and allows longer lived CL reagents to be used with fast separations. Made available in DSpace on 2015-09-25T22:14:16Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 9812772.pdf: 5577311 bytes, checksum: caef62560ab4a07e15593a72f5012595 (MD5) Previous issue date: 1997 Embargo set by: Seth Robbins for item 85673 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs U of I Only 128 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1997. http://hdl.handle.net/2142/84392 (MiAaPQ)AAI9812772 eng Chemistry, Analytical Investigations of Chemiluminescence Detection Parameters for Kinetic Analysis and Capillary Separations text Chemistry Chemistry University of Illinois at Urbana-Champaign Dissertation Ph.D.