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Pirkle, William H. Koscho, Michael Edward 2015-09-25T22:14:33Z 2015-09-25T22:14:33Z 10000-01-01 1999 1999 A number of experiments have been undertaken in order to determine, at the molecular level, the manner in which some of our recently developed low-molecular weight chiral selectors are capable of differentiating analyte enantiomers. When covalently linked to silica, these chiral selectors are capable of affording chromatographic enantioseparations. Series of homologous analytes were prepared and chromatographed on the chiral stationary phase of interest, in order to develop structure-selectivity relationships. Additionally, complexation with the chiral selector was investigated in solution (H NMR) and in the solid state (X-ray crystallography) utilizing soluble selector analogs and the analyte(s) of interest. Made available in DSpace on 2015-09-25T22:14:33Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 9944914.pdf: 7100977 bytes, checksum: 0d0414e1fda66033f93df54e87cf3ace (MD5) Previous issue date: 1999 Embargo set by: Seth Robbins for item 85729 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs U of I Only 177 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1999. http://hdl.handle.net/2142/84448 (MiAaPQ)AAI9944914 eng Chemistry, Analytical Chromatographic, Spectroscopic and Crystallographic Investigations of Chiral Recognition Processes text Chemistry Chemistry University of Illinois at Urbana-Champaign Dissertation Ph.D.