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2000 Coates, Robert M. Schenk, David John 2015-09-25T22:14:49Z 2015-09-25T22:14:49Z 10000-01-01 2000 Chiral methyl FPPs were prepared by the displacement of allylic monodeuterated diethyl phosphates with LiBEt3T. (12R)- and ( 12S)-[12-2H1, 12-3H 1]FPPs were incubated with TEAS, and the 3H NMR spectra showed that several tritiated compounds were present. The facial selectivity of the proton elimination at the cis terminal could not be determined because of low radiochemical purity. Made available in DSpace on 2015-09-25T22:14:49Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 9990130.pdf: 10034078 bytes, checksum: 2593fcf31abb64822ac68519e847e03c (MD5) Previous issue date: 2000 Embargo set by: Seth Robbins for item 85778 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs U of I Only 216 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2000. http://hdl.handle.net/2142/84497 (MiAaPQ)AAI9990130 eng Chemistry, Biochemistry Stereochemistry and Mechanism of the Enzyme -Catalyzed Cyclizations of Farnesyl Diphosphate to the Sesquiterpenes Epi -Aristolochene, Epi-Eremophilene and Vetispiradiene text Chemistry Chemistry University of Illinois at Urbana-Champaign Dissertation Ph.D.