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Shapley, John R. Wright, Chris Aaron 2015-09-25T22:14:51Z 2015-09-25T22:14:51Z 10000-01-01 2000 2000 Exploration of mercury capped rhenium carbido carbonyl clusters as potential labeling agents was initiated. The reaction of [PPh4]2[Re 7C(CO)21HgCl] with L-cysteine in aqueous acetone formed the complex [PPh4]2[Re7C(CO)21HgSCH 2CH(NH3)CO2]. In order to explore further reactions in aqueous solution, work was carried out with [Na]2[Re7C(CO) 21HgCl]. Preliminary work indicates that this complex has potential as an electron dense, easily detectable label for sulfhydryl sites in proteins. Made available in DSpace on 2015-09-25T22:14:51Z (GMT). No. of bitstreams: 2 license.txt: 4848 bytes, checksum: 96035ab3f5e1c23cc7138a224ce498bd (MD5) 9990193.pdf: 5394082 bytes, checksum: 50d4d6113461aae393018142723668df (MD5) Previous issue date: 2000 Embargo set by: Seth Robbins for item 85784 Lift date: Forever Reason: Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs Restricted to the U of I community idenfinitely during batch ingest of legacy ETDs U of I Only 178 p. Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2000. http://hdl.handle.net/2142/84503 (MiAaPQ)AAI9990193 eng Engineering, Materials Science Rhenium Carbido Carbonyl Cluster Complexes With Group 12 Metal Centers text Chemistry Chemistry University of Illinois at Urbana-Champaign Dissertation Ph.D.