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        <datestamp>2023-07-11</datestamp>
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        <thesis xmlns="http://www.ndltd.org/standards/metadata/etdms/1.1/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:dc="http://purl.org/dc/elements/1.1/" xsi:schemaLocation="http://www.ndltd.org/standards/metadata/etdms/1.1/ http://www.ndltd.org/standards/metadata/etdms/1.1/etdms11.xsd http://purl.org/dc/elements/1.1/ http://www.ndltd.org/standards/metadata/etdms/1.1/etdmsdc.xsd">
          <dc:contributor>Lu, Yi</dc:contributor>
          <dc:contributor>Lu, Yi</dc:contributor>
          <dc:contributor>Rauchfuss, Thomas B.</dc:contributor>
          <dc:contributor>van der Donk, Wilfred A.</dc:contributor>
          <dc:contributor>Fout, Alison R.</dc:contributor>
          <dc:creator>Tian, Shiliang</dc:creator>
          <dc:date>2016-07-07T21:04:08Z</dc:date>
          <dc:date>2016-07-07T21:04:08Z</dc:date>
          <dc:date>2018-07-08T09:15:16Z</dc:date>
          <dc:date>2016-01-04</dc:date>
          <dc:date>2016-05</dc:date>
          <dc:description>Submission published under a 24 month embargo labeled 'Closed Access', the embargo will last until 2018-05-01</dc:description>
          <dc:description>The student, Shiliang Tian, accepted the attached license on 2015-12-22 at 12:18.</dc:description>
          <dc:description>The student, Shiliang Tian, submitted this Dissertation for approval on 2015-12-22 at 12:22.</dc:description>
          <dc:description>This Dissertation was approved for publication on 2016-01-04 at 08:29.</dc:description>
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  Previous issue date: 2016-01-04</dc:description>
          <dc:description>Embargo set by: Seth Robbins for item 93209
Lift date: 2018-07-07T21:04:32Z
Reason: Author requested closed access (OA after 2yrs) in Vireo ETD system</dc:description>
          <dc:description>Embargo set by: Seth Robbins for item 93209
Lift date: 2018-07-07T21:14:52Z
Reason: Author requested closed access (OA after 2yrs) in Vireo ETD system</dc:description>
          <dc:description>Embargo set by: Seth Robbins for item 93209
Lift date: 2018-07-07T21:18:16Z
Reason: Author requested closed access (OA after 2yrs) in Vireo ETD system</dc:description>
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          <dc:identifier>http://hdl.handle.net/2142/90856</dc:identifier>
          <dc:language>en</dc:language>
          <dc:rights>Copyright 2015 Shiliang Tian</dc:rights>
          <dc:subject>bioinorganic chemistry</dc:subject>
          <dc:subject>protein engineering</dc:subject>
          <dc:subject>azurin</dc:subject>
          <dc:subject>copper-sulfenate</dc:subject>
          <dc:subject>S-nitrosylation</dc:subject>
          <dc:subject>dinitrosyl iron complexes (DNICs)</dc:subject>
          <dc:title>Protein engineering using azurin as the scaffold: capturing and studying novel metal-sulfenate and metal-NO species</dc:title>
          <dc:type>text</dc:type>
          <dc:type>text</dc:type>
          <degree>
            <department>Chemistry</department>
            <discipline>Chemistry</discipline>
            <grantor>University of Illinois at Urbana-Champaign</grantor>
            <level>Dissertation</level>
            <name>Ph.D.</name>
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