CHIRPED-PULSE FOURIER TRANSFORM MICROWAVE SPECTROSCOPY OF THE 2,3-DIFLUOROPYRIDINE-CARBON DIOXIDE COMPLEX

Brown, Gordon G.

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https://hdl.handle.net/2142/96917 Copy

Description

Title

CHIRPED-PULSE FOURIER TRANSFORM MICROWAVE SPECTROSCOPY OF THE 2,3-DIFLUOROPYRIDINE-CARBON DIOXIDE COMPLEX

Author(s)

Brown, Gordon G.

Contributor(s)

• Funderburk, Cameron M.
• Gaster, Sydney A

Issue Date

6/20/2017

Keyword(s)

Structure determination

Abstract

The pure rotational spectrum of the 2,3-difluoropyridine-CO$_{2}$ complex was measured on a chirped-pulsed Fourier transform microwave (CP-FTMW) spectrometer in the 3 – 18 GHz frequency range. The spectrum was analyzed to find the spectroscopic constants of the complex, including the quadrupole coupling constants and the centrifugal distortion constants. The spectrum of the 2,3-difluoropyridine-$^{13}$CO$_{2}$ complex was also measured and analyzed. Experimental constants were compared to the results of emph{ab initio} calculations.

Publisher

International Symposium on Molecular Spectroscopy

Type of Resource

text

Language

English

Permalink

http://hdl.handle.net/2142/96917

DOI

10.15278/isms.2017.TC05

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