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University of Illinois Urbana-Champaign

Analysis of the ν6 asymmetric no stretch band of nitromethane

Perry, David S.

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https://hdl.handle.net/2142/96821

Description

Title
Analysis of the ν6 asymmetric no stretch band of nitromethane
Author(s)
Perry, David S.
Contributor(s)
  • Sams, Robert L.
  • Mettee, Howard
  • Degliumberto, Lou
  • Dawadi, Mahesh B.
Issue Date
2017-06-20
Keyword(s)
  • Large amplitude motions
  • Internal rotation
Date of Ingest
  • 2017-07-27T20:14:57Z
  • 2018-01-29T23:03:54Z
Abstract
The $b$-type band near 1583 wn has been assigned for $m leq 3$, $K''_{a} leq 10$, $J'' leq 20$. The ground state combination differences derived from these assigned levels were fit with the RAM36 program with an RMS deviation of 0.0006 wn. The upper state levels are split into multiplets by perturbations. A subset of the available upper state combination differences for $m = 0$, $K'_{a} leq 7$, $J' leq 10$ were fit with the same program, but with rather poorer precision (0.01 wn) than for the ground state.
Publisher
International Symposium on Molecular Spectroscopy
Type of Resource
text
Genre of Resource
Conference Paper / Presentation
Language
eng
Permalink
http://hdl.handle.net/2142/96821
DOI
https://doi.org/10.15278/isms.2017.TD07
Copyright and License Information
Copyright 2017 David S. Perry

Owning Collections

Abstracts & Presentations - 2017 International Symposium on Molecular Spectroscopy PRIMARY