Broadband FTMW spectroscopy of the urea-argon and thiourea-argon complexes
Medcraft, Chris
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https://hdl.handle.net/2142/97039
Description
Title
Broadband FTMW spectroscopy of the urea-argon and thiourea-argon complexes
Author(s)
Medcraft, Chris
Contributor(s)
Walker, Nick
Mullaney, John C.
Cooper, Graham A.
Bittner, Dror M.
Issue Date
2017-06-22
Keyword(s)
Clusters/complexes
Date of Ingest
2017-07-27T20:15:35Z
2018-01-29T23:06:19Z
Abstract
The rotational spectra complexes of argon-urea, argon-thiourea and water-thiourea have been measured by chirped-pulse Fourier transform microwave spectroscopy from 2-18.5 GHz. The sample was produced via laser vaporisation of a rod containing copper and the organic sample as a stream of argon was passed over the surface and subsequently expanded into the vacuum chamber cooling the sample. Argon was found to bind to $pi$ system of the carbonyl bond for both the urea and thiourea complexes.
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