Microwave study of 2-phenylpyridine and their water complexes

Blanco, Susana

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https://hdl.handle.net/2142/100668 Copy

Description

Title

Microwave study of 2-phenylpyridine and their water complexes

Author(s)

Blanco, Susana

Contributor(s)

• Lopez, Juan Carlos
• Macario, Alberto

Issue Date

2018-06-21

Keyword(s)

Clusters/Complexes

Date of Ingest

• 2018-08-17T16:09:28Z
• 2018-12-12T22:36:05Z

Abstract

2-Phenylpyridine (2pp) is well known as an organic ligand in metal complexes, systems which present a relevant importance in fields such as inorganic photochemistry, biological electron-transfer dynamics or, for example, as chromophores in semiconductor assemblies in solar energy panels. The analysis of the rotational spectra of the parent and all the 13C and 15N isotopologues for the 2pp, split by the torsional vibration, have allowed us to determine the structure of 2pp. Furthermore, it has been possible to detect the spectra of the 1:1 and 1:2 water complexes. For the 1:1 adduct, the spectra of the parent and the same isotopologues as observed for the monomer have been measured. This has enabled direct structural comparison between the bare molecule and its water complex, determining how the water affects the structure of 2pp.

Publisher

International Symposium on Molecular Spectroscopy

Type of Resource

text

Genre of Resource

Conference Paper / Presentation

Language

eng

Permalink

http://hdl.handle.net/2142/100668

DOI

10.15278/isms.2018.RK05

Copyright and License Information

Copyright 2018 Susana Blanco

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