Microwave study of 2-phenylpyridine and their water complexes
Blanco, Susana
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https://hdl.handle.net/2142/100668
Description
Title
Microwave study of 2-phenylpyridine and their water complexes
Author(s)
Blanco, Susana
Contributor(s)
Lopez, Juan Carlos
Macario, Alberto
Issue Date
2018-06-21
Keyword(s)
Clusters/Complexes
Abstract
2-Phenylpyridine (2pp) is well known as an organic ligand in metal complexes, systems which present a relevant importance in fields such as inorganic photochemistry, biological electron-transfer dynamics or, for example, as chromophores in semiconductor assemblies in solar energy panels. The analysis of the rotational spectra of the parent and all the 13C and 15N isotopologues for the 2pp, split by the torsional vibration, have allowed us to determine the structure of 2pp. Furthermore, it has been possible to detect the spectra of the 1:1 and 1:2 water complexes. For the 1:1 adduct, the spectra of the parent and the same isotopologues as observed for the monomer have been measured. This has enabled direct structural comparison between the bare molecule and its water complex, determining how the water affects the structure of 2pp.
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