A rotational study of 2-methoxybenzoic acid and its water complexes
Macario, Alberto
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1211834.pptx
3302.pdf
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https://hdl.handle.net/2142/100690
Description
Title
A rotational study of 2-methoxybenzoic acid and its water complexes
Author(s)
Macario, Alberto
Contributor(s)
Lopez, Juan Carlos
Blanco, Susana
Pinacho, Pablo
Issue Date
2018-06-20
Keyword(s)
Clusters/Complexes
Date of Ingest
2018-08-17T16:09:32Z
2018-12-12T22:36:57Z
Abstract
The 2-methoxybenzoic acid (o-anisic acid) and its complexes with water have been studied in the 2-12 GHz frequency region combining chirped-pulse Fourier transform microwave spectroscopy (CP-FTMW) and molecular Fourier transform microwave spectroscopy (MB-FTMW). o-Anisic acid has been vaporized using a heating nozzle were it partially reacts through a recombination reactions to give a series of products which have been all identified from its microwave spectra. Apart from these species, three different conformations for o-anisic acid, with distinct dispositions of carboxylic group, and two for the 1:1 water complex have been observed. For the lowest energy conformer of the monomer and the most abundant water complex, the spectra of various isotopologues have been measured and the molecular structures have been determined. Relative intensity measurements have been done to provide a better understanding of the complex formation in the supersonic expansion.
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1211834.pptx
3302.pdf
