Using High-resolution Photoelectron Imaging To Probe The Spectroscopy Of Cryogenically Cooled Azolide Molecules

Zhang, Yue-Rou

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https://hdl.handle.net/2142/116585 Copy

Description

Title

Using High-resolution Photoelectron Imaging To Probe The Spectroscopy Of Cryogenically Cooled Azolide Molecules

Author(s)

Zhang, Yue-Rou

Contributor(s)

• Wang, Lai-Sheng
• Yuan, Daofu

Issue Date

2022-06-22

Keyword(s)

Mini-symposium: Benchmarking in Spectroscopy

Abstract

Photoelectron spectroscopy is a powerful technique to investigate the electronic structure and chemical bonding of anions and the corresponding neutrals upon electron detachment. Here, we use our electrospray ionization photoelectron spectroscopy apparatus, which couples a cryogenically-cooled 3D Paul trap and a high resolution imaging system to get the vibrational and electronic information about three azolide: pyrazolide, pyrrolide and imidazolide. Besides the expected conventional dipole bound state, a core-excited dipole bound state is observed in pyrazolide with the neutral core in its first excited electronic state. And a completely different threshold behavior is observed for pyrrolide and imidazolide with a similar pi type HOMO: a d-wave-dominated spectrum is found for pyrrolide and an s-wave-dominated spectrum is found for imidazolide.

Publisher

International Symposium on Molecular Spectroscopy

Type of Resource

text

Language

eng

Handle URL

https://hdl.handle.net/2142/116585&&

DOI

https://doi.org/10.15278/isms.2022.WI02

Copyright and License Information

Copyright 2022 held by the authors

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