Electronic Spectroscopy Of The Previously Unknown Palladium Monosulfide (pds) Radical

Zhang, Lei

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https://hdl.handle.net/2142/116632 Copy

Description

Title

Electronic Spectroscopy Of The Previously Unknown Palladium Monosulfide (pds) Radical

Author(s)

Zhang, Lei

Contributor(s)

• Yang, Jie
• Ma, Xinwen
• Yu, Yao

Issue Date

2022-06-22

Keyword(s)

Mini-symposium: Benchmarking in Spectroscopy

Abstract

\begin{wrapfigure}{l}{0pt} \includegraphics[scale=0.11]{figure1.eps} \end{wrapfigure} The optical spectra of the diatomic PdS radical in the gas phase have been investigated for the first time through a combination of laser-induced fluorescence (LIF) and single vibronic level emission spectroscopy. The [22.3] $^3\Sigma^-$ $-$ $X$ $^3\Sigma^-$ transition system containing sixteen vibrational bands was identified in the LIF spectra in the energy range of 22,030 $-$ 23,400 cm$^{-1}$. Rotationally resolved spectra and analysis enabled a determination of the molecular structures in the upper and lower states, involving the rotational constants, the vibrational constants, the spin-orbit splittings, and the vibrational isotope shifts. The emission transitions from the [22.3] state down to the ground state and to the low-lying $A$ $^3\Pi$ state were recorded, by which the spin-orbit splittings of $A$ $^3\Pi_{2,1,0^{-,+}}$ were determined. A comparison of the bond lengths (and the vibrational frequencies) of the VIII group monosulfide radicals (NiS/PdS/PtS) reveals the relativistic effects in the Pd and Pt atoms.

Publisher

International Symposium on Molecular Spectroscopy

Type of Resource

text

Language

eng

Handle URL

https://hdl.handle.net/2142/116632&&

DOI

https://doi.org/10.15278/isms.2022.WI04

Copyright and License Information

Copyright 2022 held by the authors

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