University of Illinois Urbana-Champaign

The Millimeter Wave Spectra Of Vinyl Isocyanate And Vinyl Ketene, Candidates For Astronomical Observations

Kolesniková, Lucie

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https://hdl.handle.net/2142/116766

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Title
The Millimeter Wave Spectra Of Vinyl Isocyanate And Vinyl Ketene, Candidates For Astronomical Observations
Author(s)
Kolesniková, Lucie
Contributor(s)
  • Urban, Stepan
  • Guillemin, J.-C.
  • Kania, Patrik
  • Uhlíková, Tereza
  • Luková, Kateřina
  • Vávra, Karel
  • Koucký, Jan
Issue Date
2022-06-22
Keyword(s)
Astronomy
Abstract
Interstellar detections of isocyanic acid\footnote{Snyder, L. E. \& Buhl, D. 1972, ApJ, 177, 619.} , methyl isocyanate\footnote{Halfen, D. T., Ilyushin, V. V., \& Ziurys, L. M. 2015, ApJ, 812, L5. Cernicharo, J., Kisiel, Z., Tercero, B., et al. 2016, A\&A, 587, L4.}, and very recently also ethyl isocyanate\footnote{Rodr\'{i}guez-Almeida, L. F., Rivilla, V. M., Jim\'{e}nez-Serra, I., et al. 2021, A\&A, 654, L1.} open the question of the possible detection of the related molecule vinyl isocyanate in the interstellar medium. Similarly, astronomical observations of ketene\footnote{Turner, B. E. 1977, ApJ, 213, L75.} places vinyl ketene among the species of potential interstellar relevance. In the present work, both vinyl species were generated by thermolysis of suitable precursors at $500^{\circ}$C and their room-temperature rotational spectra were recorded between 218 and 330 GHz using the Prague millimeter wave spectrometer\footnote{Kania, P., St\v{r}\'{i}tesk\'{a}, L., \v{S}ime\v{c}kov\'{a}, M., \& \v{S}. Urban. 2006, J. Mol. Struct., 795, 209.}. The spectroscopic measurements and analyses presented here will allow to search for both molecules in the millimeter wave surveys of interstellar sources such as those recorded by Atacama Large Millimeter/submillimeter Array. \vspace{0.5cm} \textbf{Acknowledgments:} L.K., J.K., K.V., K.L., and P.K. acknowledge the financial fundings from the Czech Science Foundation (GACR, grant No.~19-25116Y) and the Ministry of Education, Youth and Sports of the Czech Republic (MSMT, grant No.~8J21FR006). J.C.G. thanks the Barrande project No.~46662VH and the Centre National d'Etudes Spatiales (CNES) for a grant BC~U32-4500065585.
Publisher
International Symposium on Molecular Spectroscopy
Type of Resource
text
Genre of Resource
Conference Paper / Presentation
Language
eng
Handle URL
https://hdl.handle.net/2142/116766
DOI
https://doi.org/10.15278/isms.2022.WN10
Copyright and License Information
Copyright 2022 held by the authors

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