Gas-phase Charge Transfer Electronic Spectroscopy Of Ag+-benzene Complex
Orr, Dylan S.
Loading…
Permalink
https://hdl.handle.net/2142/116850
Description
Title
Gas-phase Charge Transfer Electronic Spectroscopy Of Ag+-benzene Complex
Author(s)
Orr, Dylan S.
Contributor(s)
Duncan, Michael A.
Colley, Jason E.
Issue Date
2022-06-22
Keyword(s)
Ions
Abstract
Charge transfer electronic spectroscopic results were reported for the Ag+-benzene complex in the gas phase using photodissociation. The Ag+-benzene complex was generated by laser vaporization of a silver rod in combination with pulsing an inert gas seeded with benzene then mass selected and probed using a time-of-flight mass spectrometer. The mass-selected ions were then fragmented and scanned using a solid state OPO capable of scanning through the UV-Visible range. A high-resolution electronic spectrum of Ag+-benzene was reported in the UV-Visible range to determine the upper threshold for the dissociation energy of the Ag+-benzene complex which were compared with previous velocity map imaging results. An unexpected feature was observed in the lower UV region which was attributed to the HOMO-LUMO absorption on an excited benzene ligand.
Use this login method if you
don't
have an
@illinois.edu
email address.
(Oops, I do have one)
IDEALS migrated to a new platform on June 23, 2022. If you created
your account prior to this date, you will have to reset your password
using the forgot-password link below.
