Global coal ball stable isotope analysis to define permineralizing environments
Beddow, Hannah
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Permalink
https://hdl.handle.net/2142/130230
Description
Title
Global coal ball stable isotope analysis to define permineralizing environments
Author(s)
Beddow, Hannah
Issue Date
2025-07-25
Director of Research (if dissertation) or Advisor (if thesis)
Punyasena, Surangi W.
Committee Member(s)
Christie, Max
Johnson, Tom
Elrick, Scott
Conroy, Jessica
Department of Study
Plant Biology
Discipline
Plant Biology
Degree Granting Institution
University of Illinois Urbana-Champaign
Degree Name
M.S.
Degree Level
Thesis
Keyword(s)
Coal
Ball
Stable
Isotope
Geochemistry
Carboniferous
Swamp
Paleobotony
Abstract
Coal balls are permineralized calcareous remains of plant material from peat swamps of the late Carboniferous and early Permian, formed under conditions unique to the time period by processes that are still not fully understood. While multiple pathways have been proposed for the formation of coal balls, there is currently no consensus. Geochemical, petrological, and cyclostratigraphic results from previous studies have provided conflicting evidence suggesting that meteoric water or marine water is the source of the calcium carbonate ions responsible for permineralizing areas of the peat swamp. Similarly, there is a lack of consensus regarding the specific triggering mechanism by which calcite begins to precipitate within the peat. We aimed to establish a comprehensive global geochemical dataset of stable isotope values, with the goal of characterizing the environments and conditions necessary for the formation of coal balls. Our δ13C, δ18O, and 87Sr/86Sr measurements were within the range of a meteoric water source with a small number of outliers that suggested a marine water source. We interpret these results as indicating that coal balls formed in a predominantly meteoric water environment, with occasional inputs of marine water into the peat swamp.
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