Waveguide chipred-pulse fourier transform microwave spectroscopy of allyl bromide

McCabe, Morgan N.

Permalink

https://hdl.handle.net/2142/51006 Copy

Description

Title

Waveguide chipred-pulse fourier transform microwave spectroscopy of allyl bromide

Author(s)

McCabe, Morgan N.

Contributor(s)

Shipman, Steven

Issue Date

2014-06-19

Keyword(s)

Chirped pulse

Date of Ingest

• 2014-09-17T16:55:47Z
• 2015-04-14T18:43:03Z

Abstract

The rotational spectrum of allyl bromide was recorded from 8.7 to 26.5 GHz at -20 $^{\circ}$C with a waveguide chirped-pulse Fourier transform microwave spectrometer. The rotational spectrum of allyl bromide has been previously studied by Niide and coworkers. \footnote{Y.~Niide,~M,~Takano,T.~Satoh,~and Y.~Sasada~J.~Mol. Spectrosc., 63, 108(1976)}$^,$\footnote {Niide,~Yuzuru, J. Sci. Hiroshima Univ., Ser. A, 48, 1(1984)} However, previous assignments of this spectrum only extended to J = 12 and K$_a$ = 1. Newly acquired data from our spectrometer has allowed us to extend the previous work to higher values of J and K$_a$, leading to significant improvements in the distortion constants in particular. Comparisons between the spectra and conformational preferences of the allyl halides will also be discussed.

Publisher

International Symposium on Molecular Spectroscopy

Type of Resource

text

Genre of Resource

Conference Paper / Presentation

Language

English

Permalink

http://hdl.handle.net/2142/51006

DOI

https://doi.org/10.15278/isms.2014.RE09

Copyright and License Information

Copyright 2014 by the authors. Licensed under a Creative Commons Attribution 4.0 International License. http://creativecommons.org/licenses/by/4.0/

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