Explorations in Supramolecular Chemistry: Part 1. Development of a Modular System for the Study of Self-Organization Through Microphase Segregation in Discotic Liquid Crystals. Part 2. Investigation of Deazapterins and Naphthyridines as End-Groups for Supramolecular Polymers
Zimmerman, Ned Walter
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https://hdl.handle.net/2142/84133
Description
Title
Explorations in Supramolecular Chemistry: Part 1. Development of a Modular System for the Study of Self-Organization Through Microphase Segregation in Discotic Liquid Crystals. Part 2. Investigation of Deazapterins and Naphthyridines as End-Groups for Supramolecular Polymers
Author(s)
Zimmerman, Ned Walter
Issue Date
2003
Doctoral Committee Chair(s)
Moore, Jeffrey S.
Zimmerman, Steven C.
Department of Study
Chemisty
Discipline
Chemisty
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Keyword(s)
Chemistry, Organic
Language
eng
Abstract
In the second investigation, the use of multiple highly directional hydrogen bonds for the formation of supramolecular polymers was explored. Synthetic routes toward supramolecular polymer end-groups based upon the 2-amino-5-deazapterin and 2,7-diamino-[1,8]-naphthyridine ring systems were pursued. While it was found that the end-groups could be made, the synthetic difficulties and inefficiencies encountered precluded the isolation of sufficient sample quantities for the exploration of the materials' properties. The further development of end-groups based upon these ring systems was discontinued.
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