University of Illinois Urbana-Champaign

Synthesis and Reactivity of Trimethylsilylthiolate Compounds: Precursors for Heterometallic Complexes

Liang, Hong-Chang

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Description

Title
Synthesis and Reactivity of Trimethylsilylthiolate Compounds: Precursors for Heterometallic Complexes
Author(s)
Liang, Hong-Chang
Issue Date
1997
Doctoral Committee Chair(s)
Shapley, Patricia A.
Department of Study
Chemistry
Discipline
Chemistry
Degree Granting Institution
University of Illinois at Urbana-Champaign
Degree Name
Ph.D.
Degree Level
Dissertation
Date of Ingest
2015-09-25T22:14:14Z
Keyword(s)
Chemistry, Inorganic
Language
eng
Abstract
Chapter 4. The synthesis and reactivity of several ruthenium(VI) and osmium(VI) sulfido complexes are reported. The triruthenium sulfido complexes (PPh$\sb4$) ($\rm\{Ru(N)R\sb2\}\sb3(\mu\sb3$-S)$\sb2\rbrack,$ (19, R = Me; 20, R = $\rm CH\sb2SiMe\sb3)$ react with $\rm MeOSO\sb2CF\sb3$ to form $\mu\sb3$-thiolate complexes $\rm\{Ru(N)R\sb2\}\sb3(\mu\sb3$-SMe)($\mu\sb3$-S) (22, R = $\rm CH\sb2SiMe\sb3$; 23, R = Me). Complex 19 reacts with ($\rm Cu(PPh\sb3)\sb2(NCMe)\sb2\rbrack\lbrack BF\sb4\rbrack$ to form ($\rm Cu(PPh\sb3)\sb2\rbrack\lbrack\{Ru(N)R\sb2\}\sb3(\mu\sb3$-S)$\sb2\rbrack,$ 24.
Graduation Semester
1997
Type of Resource
text
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http://hdl.handle.net/2142/84384

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