OPTIMIZATION OF EXTREME ULTRAVIOLET LIGHT SOURCE FROM HIGH HARMONIC GENERATION FOR CONDENSED-PHASE CORE-LEVEL SPECTROSCOPY

Lin, Ming-Fu

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Description

Title

OPTIMIZATION OF EXTREME ULTRAVIOLET LIGHT SOURCE FROM HIGH HARMONIC GENERATION FOR CONDENSED-PHASE CORE-LEVEL SPECTROSCOPY

Author(s)

Lin, Ming-Fu

Contributor(s)

• Vura-Weis, Josh
• Carlson, Michaela
• Zhang, Kaili
• Benke, Kristin
• Ryland, Elizabeth S.
• Verkamp, Max A.

Issue Date

25-Jun-15

Keyword(s)

Instrument/Technique Demonstration

Abstract

Extreme ultraviolet (XUV) light source from high-order harmonic generation has been shown to be a powerful tool for core-level spectroscopy. In addition, this light source provides very high temporal resolution (10$^{-18}$ s to 10$^{-15}$ s) for time-resolved transient absorption spectroscopy. Most applications of the light source have been limited to the studies of atomic and molecular systems, with technique development focused on optimizing for shorter pulses (i.e. tens of attoseconds) or higher XUV energy (i.e. ~keV range). For the application to general molecular systems in solid and liquid forms, however, the XUV photon flux and stability are highly demanded due to the strong absorption by substrates and solvents. In this case, the main limitation is due to the stability of the high order generation process and the limited bandwidth of the XUV source that gives only discrete even/odd order peaks. Consequently, this results in harmonic artifact noise that overlaps with the resonant signal. In our current study, we utilize a semi-infinite cell for high harmonic generation from two quantum trajectories (i.e. short and long) at over-driven NIR power. This condition, produces broad XUV spectrum without using complicated optics (e.g. hollow-core fibers and double optical gating). This light source allows us to measure the static absorption spectrum of the iron M-edge from a Fe(acac)$_{3}$ molecular solid film, which shows a resonant feature of 0.01 OD (~2.3% absorption). Moreover, we also investigate how sample roughness affects the static absorption spectrum. We are able to make smooth solar cell precursor materials (i.e. PbI$_{2}$ and PbBr$_{2}$) by spin casting and observe iodine (50 eV) and bromine (70 eV) absorption edges in the order of 0.05 OD with minimal harmonic artifact noise.

Publisher

International Symposium on Molecular Spectroscopy

Type of Resource

text

Language

English

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http://hdl.handle.net/2142/79403

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