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University of Illinois Urbana-Champaign
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HIGH-RESOLUTION LASER SPECTROSCOPY OF
14NO3 RADICAL: VIBRATIONALLY EXCITED STATES
OF THE B2E_ STATE
Tada, Kohei
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https://hdl.handle.net/2142/79435
Description
Title
HIGH-RESOLUTION LASER SPECTROSCOPY OF
14NO3 RADICAL: VIBRATIONALLY EXCITED STATES
OF THE B2E_ STATE
Author(s)
Tada, Kohei
Contributor(s)
Hirota, Eizi
Ishiwata, Takashi
Kasahara, Shunji
Issue Date
23-Jun-15
Keyword(s)
Radicals
Date of Ingest
2016-01-05T20:02:06Z
Abstract
High-resolution fluorescence excitation spectra of chem{^{14}NO_3} radical were intermittently recorded in the region 15860 cm$^{-1}$ to 16050 cm$^{-1}$ corresponding to the transitions to the vibrationally excited states of the $B^{2}E^{prime}$ state. Well-separated rotational lines were found to disappear as the vibrational energy increases. The 16050 cm$^{-1}$ region is almost unstructured even in the high-resolution measurement, and its rotational analysis is almost impossible. The rotational assignment of the 15870 cm$^{-1}$ region is possible and it has been undertaken by the ground state combination differences and the Zeeman effect observation.
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