Rotational investigation of the adducts of formic acid with alcohols, ethers and esters
Caminati, Walther
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https://hdl.handle.net/2142/91455
Description
Title
Rotational investigation of the adducts of formic acid with alcohols, ethers and esters
Author(s)
Caminati, Walther
Contributor(s)
Li, Weixing
Spada, Lorenzo
Evangelisti, Luca
Issue Date
2016-06-21
Keyword(s)
Clusters/Complexes
Abstract
Mixtures of formic acid with methyl alcohol, with isopropyl alcohol, with \textit{tert}-butyl alcohol, with dimethylether
and with isopropylformiate have been supersonically expanded as pulsed jets. The obtained cool plumes have been
analyzed by Fourier transform microwave spectroscopy. It has been possible to assign the rotational spectra
of the 1:1 adducts of formic acid with \textit{tert}-butyl alcohol, with dimethyl ether and with isopropylformiate.
The conformational shapes and geometries of these adducts, as well as the topologies of their itermolecular hydrogen
bonds will be presented.
An explanation is given of the failure of the assignments of the rotational spectra of the adducts of formic acid with
methyl alcohol and isopropyl alcohol.
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