University of Illinois Urbana-Champaign

The electronic spectrum of cryogenic ruthenium-tris-bipyridine dications

Weber, J. Mathias

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598577.pptx

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https://hdl.handle.net/2142/91128

Description

Title
The electronic spectrum of cryogenic ruthenium-tris-bipyridine dications
Author(s)
Weber, J. Mathias
Contributor(s)
  • Smith, James E. T.
  • Xu, Shuang
Issue Date
2016-06-21
Keyword(s)
Spectroscopy in Traps
Date of Ingest
2017-01-26T21:38:36Z
Abstract
We present the electronic spectrum of Ru(II)-tris(2,2’-bipyridine), Ru(bpy)$_3^{2+}$, measured by photodissociation spectroscopy of mass selected Ru(bpy)$_3^{2+}\cdot$N$_2$ ions prepared in a cryogenic quadrupole ion trap. The spectrum is composed of several metal-to-ligand charge transfer (MLCT) transitions, as well as metal centered bands and ligand centered $\pi \pi^$ states. We observe several partially resolved electronic transitions in the MLCT band. We discuss the results in the framework of time-dependent density functional theory.
Publisher
International Symposium on Molecular Spectroscopy
Type of Resource
text
Genre of Resource
Conference Paper / Presentation
Language
En
Permalink
http://hdl.handle.net/2142/91128
Copyright and License Information
Copyright 2016 by the authors

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Abstracts & Presentations - 2016 International Symposium on Molecular Spectroscopy PRIMARY