Millimeter wave spectrum of nitromethane

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https://hdl.handle.net/2142/91391

Title: Millimeter wave spectrum of nitromethane
Author(s): Ilyushin, V.
Issue Date: 2016-06-21
Keyword(s): Spectroscopy of Large Amplitude Motions
Abstract: A new study of the millimeter wave spectrum of nitromethane \chem{CH_3NO_2} is reported. The new measurements covering the frequency range from 49 GHz to 236 GHz have been carried out using spectrometer in IRA NASU (Ukraine). The transitions belonging to the m $\leq$ 8 torsional states have been analyzed using the RAM36 program\footnote{V. Ilyushin, Z. Kisiel, L. Pszczółkowski, H. Mäder, J. T. Hougen J. Mol. Spectrosc. 259 (2010) 26-38.}, which has been modified for this study to take into account the quadrupole hyperfine structure due to presence of the nitrogen atom. The dataset consisting of 5838 microwave line frequencies and including transitions with {\it J} up to 50 was fit using a model consisting of 93 parameters and weighted root-mean-square deviation of 0.89 has been achieved. In the talk the details of this new study will be discussed.
Publisher: International Symposium on Molecular Spectroscopy
Type of Resource: text
Language: En
Permalink: http://hdl.handle.net/2142/91391